Solvent-free aromatic C–H functionalisation/halogenation reactions
✍ Scribed by Bedford, Robin B.; Engelhart, Jens U.; Haddow, Mairi F.; Mitchell, Charlotte J.; Webster, Ruth L.
- Book ID
- 111652715
- Publisher
- Royal Society of Chemistry
- Year
- 2010
- Tongue
- English
- Weight
- 504 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1477-9226
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One-pot cascade reactions of N-acylglycines, acetic anhydride, anhydrous sodium acetate, aromatic aldehydes, and ammonium N-aryldithiocarbamates expeditiously and diastereoselectively yield 5-acylamino-3,6-diarylperhydro-2-thioxo-1,3-thiazin-4-ones (5a-j) in solvent-free conditions under microwave i
Rates and thermodynamic data have been obtained for the reversible self-termination reaction: 2k1 R' + R' G=-D Involving aromatic 2-(4'dimethylaminophenyl)indandione-1,3-y1 (I), 244'diphenylaminophenyl)indandione-1,3-y1 (II), and 2,6 di-tert-butyl-4-(p-phthalylvinyl)-phenoxyl (III) radicals in diffe