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Solvent Effects on the Redox Properties of Cu Complexes Used as Mediators in Atom Transfer Radical Polymerization

✍ Scribed by Coullerez, Géraldine; Malmström, Eva; Jonsson, Mats


Book ID
126894564
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
69 KB
Volume
110
Category
Article
ISSN
1089-5639

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## Abstract Summary: The effect of [L]/[Cu^I^] ratio, ligand, the choice of solvent and temperature on the activation rate constants in ATRP with catalyst complexes formed with two pyridylmethanimine ligands [PMI, i.e., __N__‐propyl‐pyridylmethanimine (NPPMI) and __N__‐octyl‐pyridylmethanimine (NOP