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Effect of Solvent on the Activation Rate Parameters for Polystyrene and Poly(butyl acrylate) Macroinitiators in Atom Transfer Radical Polymerization

✍ Scribed by Chambard, Grégory; Klumperman, Bert; German, Anton L.


Book ID
126037475
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
62 KB
Volume
33
Category
Article
ISSN
0024-9297

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## Abstract Summary: The effect of [L]/[Cu^I^] ratio, ligand, the choice of solvent and temperature on the activation rate constants in ATRP with catalyst complexes formed with two pyridylmethanimine ligands [PMI, i.e., __N__‐propyl‐pyridylmethanimine (NPPMI) and __N__‐octyl‐pyridylmethanimine (NOP