Rate constants have been measured by pulse radiolysis for the reactions of the carbonate radical, COa'-, with a number of organic and inorganic reactants as a function of temperature, generally over the range 5 to 80Β°C. The reactants include the substitution-inert cyano complexes of Fe", Mo", and W"
β¦ LIBER β¦
Solvent effects on the rate constants for reaction of trichloromethylperoxyl radicals with organic reductants
β Scribed by Alfassi, Z. B.; Huie, R. E.; Neta, P.
- Book ID
- 111978569
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 559 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0022-3654
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## Abstract Rate constants for the selfβreaction of __tert__butyl radicals in six __n__alkanes are determined as functions of temperature by kinetic electronβspin resonance spectroscopy and from rates of product formation. They are well described by a SmoluchowskiβStokesβEinstein treatment includin