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Solvent effects on the luminescing excited states of iridium(III) complexes

✍ Scribed by T.L. Cremers; G.A. Crosby

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 354 KB
Volume: 73
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)80713-5

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✦ Synopsis

The photolummescence of czsd~chlorobls(l,lO-phenanthroline)inchum(III) chloride and crsdichlorobls(4,4'dimethy~-2,2'-blpyridme)Irilum(IIl) chlonde has been mvestlgated from 2-77 K Based on spectral band shape, errussion decay time, and sWt of orgin wrth change III solvent polanty the luminescmg exated state of each species can be &s&red as metalligand charge transfer.

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