Solvent effects on the kinetics of simple electrochemical reactions: Further examination of metal ethylenediamine and ammine redox couples
β Scribed by Jane Kim Farmer; Thomas Gennett; Michael J. Weaver
- Book ID
- 108343910
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 592 KB
- Volume
- 191
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
The kinetics of the solvolytic aquation of cis-(Bromo) (imidazole) bis(ethy1enediamine) cobalt (111) and cis-(Bromo) (N-methylimidazole) bis(ethy1enediamine) cobalt(II1) have been investigated in aqueous methanol media with methanol content 0-80% by weight and a t temperatures 40-55Β°C. The pseudo-fi
## Abstract The solvolysis of __cis__(chloro)(1βaminoβpropanβ2βol)bis(ethylenediamine)cobalt(III) in aqueous alcoholic media using methanol, propanβ2βol, __t__βbutanol as cosolvents, resulted in the formation of the (N,O) chelated product__cis__[Co(en)~2~(NH~2~CH~2~CHOHCH~3~)]^3+^. The pseudo first