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Solvent effects on the kinetics of simple electrochemical reactions: Further examination of metal ethylenediamine and ammine redox couples

✍ Scribed by Jane Kim Farmer; Thomas Gennett; Michael J. Weaver


Book ID
108343910
Publisher
Elsevier Science
Year
1985
Weight
592 KB
Volume
191
Category
Article
ISSN
0022-0728

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πŸ“œ SIMILAR VOLUMES


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✍ Anadi C. Dash; Neelamadhab Dash πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 591 KB

The kinetics of the solvolytic aquation of cis-(Bromo) (imidazole) bis(ethy1enediamine) cobalt (111) and cis-(Bromo) (N-methylimidazole) bis(ethy1enediamine) cobalt(II1) have been investigated in aqueous methanol media with methanol content 0-80% by weight and a t temperatures 40-55Β°C. The pseudo-fi

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✍ Anadi C. Dash; Prafulla K. Das πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 574 KB

## Abstract The solvolysis of __cis__(chloro)(1‐amino‐propan‐2‐ol)bis(ethylenediamine)cobalt(III) in aqueous alcoholic media using methanol, propan‐2‐ol, __t__‐butanol as cosolvents, resulted in the formation of the (N,O) chelated product__cis__[Co(en)~2~(NH~2~CH~2~CHOHCH~3~)]^3+^. The pseudo first