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Solvent effects on the kinetics of redox reactions between ions and alcohols. Effect of solvent structure

✍ Scribed by Wells, C. F.

Book ID
120290108
Publisher
Royal Society of Chemistry
Year
1970
Weight
703 KB
Volume
66
Category
Article
ISSN
0014-7672

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Abnormal salt effects on reactions betwe
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## Abstract Salt effects on the reactions [Fe(CN)~6~]^4βˆ’^ + S~2~O^=^~8~ and [Ru(NH~3~)~5~py]^2+^ + S~2~O have been studied in media of different dielectric constants constituted by mixtures of water with organic cosolvents. It is known that salt and solvent effects are coupled and, consequently, ca