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Solvent effects on the infrared frequency of the N-C band in isonitriles and the sign of ∂μt6r

✍ Scribed by W.D. Horrocks Jr.; R.H. Mann


Publisher
Elsevier Science
Year
1963
Weight
827 KB
Volume
19
Category
Article
ISSN
0371-1951

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A low temperature infrared study of the
✍ M. Asselin; C. Sandorfy 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 260 KB

Self-associated alcohols are studied in solution down to liquid nitrogen tempeiature. :t is found that the fundamentalxnd first overtone shift linearly and by the same amount with temperature and that anharmonicity decreases with decreasing temperature. The band width also decreases and only-one ban