✦ LIBER ✦

A low temperature infrared study of the band-width and frequency in self-associated alcohols

✍ Scribed by M. Asselin; C. Sandorfy

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 260 KB
Volume: 8
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)80104-5

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✦ Synopsis

Self-associated alcohols are studied in solution down to liquid nitrogen tempeiature. :t is found that the fundamentalxnd first overtone shift linearly and by the same amount with temperature and that anharmonicity decreases with decreasing temperature. The band width also decreases and only-one band remains, having a normal shape. The results are interpretable in terms of a statistical distkibution of 0 . _ .O distances.