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Solvent Effects on the Enthalpy and Entropy of

✍ Scribed by José A. Manso; M. Teresa Pérez-Prior; María del Pilar García-Santos; Emilio Calle; Julio Casado

Book ID
106430085
Publisher
Springer US
Year
2008
Tongue
English
Weight
323 KB
Volume
37
Category
Article
ISSN
0095-9782

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Enthalpy and Entropy Contributions to So
Enthalpy and Entropy Contributions to Solvent Quality and Inversions of Heat Effects with Polymer Concentration
✍ Maria Bercea; Bernhard A. Wolf 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 249 KB

## Abstract Summary: Vapor pressures above the solutions of polystyrene in either cyclohexane (32–60 °C) or toluene (10–70 °C) have been measured by a combination of head space sampling and gas chromatography as a function of the volume fraction __φ__ of the polymer. The thus obtained Flory‐Huggins