The strain and entropy effects of the lactone formation from Ͷ-bromoalkane-carboxylate ions in ring sizes 3 to 23 is reevaluated. We find that ⌬H ‡ is the largest contributor to the observed rates (⌬G ‡ ) for ring sizes 3 to 6, while ϪT ⌬S ‡ has little influence, ϪT ⌬S ‡ has more effect on the obser
✦ LIBER ✦
Enthalpy and entropy effects in adsorption and displacement
✍ Scribed by Zoltán Király; Imre Dékány
- Publisher
- Elsevier Science
- Year
- 1990
- Weight
- 396 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0166-6622
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