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Solvent effects on relaxation of the 1B2u state of benzene

✍ Scribed by Simons S. Cohen

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 344 KB
Volume: 18
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)80193-9

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✦ Synopsis

Values of triplet yields for dilute solutions of benzene in methylcyclohesnne, cyciohesane, methanol, ethanol, acetonitrile, perfluoro-n-hexane, and water, and also fluoreaccnce yields and lifetimes in perfluoro-n-hesane arc reported. The calculated rate constants for fluorescence and intersystem crossing are only slightly affected by wlvent. except for water. The enhancement of "internal conversion" by increasing solvent polarity is interpreted zs a result of an increase in the pre-esponential factor for a possible *(rr, n*) + '(a, 3%) transition. '. '._ 371 .', VoluAe 18, numbcr 3 CHEMICAL PHYSICS LETTERS 1 Febrxlry 197.1 . .

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