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Intensity-dependent laser ionization experiments involving the 1b1u state of benzene

✍ Scribed by Ellen Sekreta; Kevin G. Owens; James P. Reilly

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 503 KB
Volume: 132
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80644-3

No coin nor oath required. For personal study only.

✦ Synopsis

Benzene is two-step photoionized with ArF laser radiation and the resulting mass-and photoelectron spectra obtained versus laser intensity. In agreement with previous work, benzene ionizes very inefficiently at this wavelength. Attempts to probe the rapid non-radiative relaxation of its 'B it, excited state by monitoring the intensity dependence of the photoelectron spectrum are impeded by ionization of neutral atomic carbon fragments.

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