Solvent effects on Raman band intensities
β Scribed by Giancarlo Fini; Paolo Mirone; Paolo Patella
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 669 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
The "dielectric theory" of solvent effect on Raman intensity has been modified in order to take into account the anisotropic character of molecular polarizability. The resulting expression for the scattering coefficient agrees well with experimental results for strongly anisotropic mo!ecules. In th
Raman spectra of toluene at pressures up to 4.1 kbar and temperatures up to lOO"C, have been studied. The frequency and intensity changes of the symmetric &,) and antisymmetric (v& ring breathing vibrations have been related principally to changes in density. Increasing density at constant temperatu