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Solvent effects in the reactivity of phenylethyl hydroperoxide, II. Reactivity and β-scission of α-phenylethoxy radicals in the solutions of α-phenylethylhydroperoxide

✍ Scribed by Móger, G. ;Mazaleczkaja, L. I. ;Gál, D.

Book ID
112691071
Publisher
Springer
Year
1993
Tongue
English
Weight
116 KB
Volume
49
Category
Article
ISSN
0133-1736

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The thermolysis of the steroidal 5a,8a -peroxide 1, under acidic conditions afforded in addition to the expected 5,lO: 8,9-diseco derivative 2, the rearranged 5a,Ea-epoxide 3, the structure of which was determined by NMR spectroscopy and X-ray analysis. The authors from Yugoslavia are grateful to t