Proton chemical shifts as well as solvent shifts induced by benzene in several amidoximes are examined with respect to their configuration and are compared to the solvent shifts induced in benzalanilines. The geometry of the benzene-solute 'collision-complex' is also discussed.
Solvent effects in NMR spectra induced by benzene in aromatic N-alkyl nitrones and O-alkyl oximes—III
✍ Scribed by N. E. Alexandrou; A. G. Varvoglis
- Publisher
- John Wiley and Sons
- Year
- 1971
- Tongue
- English
- Weight
- 322 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
NMR solvent effects induced by benzene on several N‐ and O‐alkyl oximes are reported. Both shielding and deshielding effects are observed and are accounted for by the geometry of the solute‐solvent ‘complex’. Good Hammett plots of solvent shifts for various types of protons are obtained.
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