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Solvent effects in NMR spectra induced by benzene in amidoximes—V

✍ Scribed by N. E. Alexandrou; D. N. Nicolaides

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
283 KB
Volume
4
Category
Article
ISSN
0749-1581

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✦ Synopsis

Proton chemical shifts as well as solvent shifts induced by benzene in several amidoximes are examined with respect to their configuration and are compared to the solvent shifts induced in benzalanilines. The geometry of the benzene-solute 'collision-complex' is also discussed.

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## Abstract Proton chemical shifts, as well as solvent shifts induced by benzene, can be used for the structure determination of 4,5‐asymmetrically substituted 1‐(__N__‐isoimido)‐1,2,3‐triazoles, derived from the oxidation of α‐diketone bisaroylhydrazones. The geometry of the postulated ‘collision