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Solvent effects in electroneutral reactions. I. Combination and disproportionation of ethyl radicals in solution

✍ Scribed by Stefani, Andrew P.

Book ID
111891409
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
808 KB
Volume
90
Category
Article
ISSN
0002-7863

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The kinetics of the bimolecular self-rea
The kinetics of the bimolecular self-reaction of t-butyl radicals in solution. II. Disproportionation/combination ratios
✍ Hans-Herbert Schuh; Hanns Fischer πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 952 KB

## Abstract Disproportionation/combination ratios P~d~/P~c~ of self‐reacting __t__‐butyl radicals are determined as a function of solvent and temperature. the observed large solvent and temperature dependences are ascribed to anisotropic reorientational motions of the radicals during their encounte