Solvent effects during reactions in supercritical water
β Scribed by Townsend, Susan H.; Abraham, Martin A.; Huppert, Gilbert L.; Klein, Michael T.; Paspek, Stephen C.
- Book ID
- 126335737
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 870 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0888-5885
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π SIMILAR VOLUMES
The extreme pressure dependence of the solvent properties -density, dielectric constant, and solubility parameter -has been exploited in the scrutiny of the mechanism of hydrolysis in supercritical water. Molecules containing the structural moiety of a saturated carbon attached to a heteroatom-conta
A variety of Diels-Alder reactions have been performed in supercritical water as a reaction medium. The rapid reaction of Diels-Alder reactions of cyclopentadiene and various electron poor dienophiles such as diethyl fumarate and acrylonitrile is observed in supercritical water, and leads to high yi