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Diels-Alder reactions using supercritical water as an aqueous solvent medium

✍ Scribed by Michael B. Korzenski; Joseph W. Kolis

Book ID: 104257628
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 199 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01274-4

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✦ Synopsis

A variety of Diels-Alder reactions have been performed in supercritical water as a reaction medium. The rapid reaction of Diels-Alder reactions of cyclopentadiene and various electron poor dienophiles such as diethyl fumarate and acrylonitrile is observed in supercritical water, and leads to high yields of clean products without added catalysts.

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