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Solvent Effect on the Rate of β-Scission of the tert- Butoxyl Radical

✍ Scribed by Tsentalovich, Yuri P.; Kulik, Leonid V.; Gritsan, Nina P.; Yurkovskaya, Alexandra V.

Book ID
127076749
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
71 KB
Volume
102
Category
Article
ISSN
1089-5639

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On the mechanism of reaction of tert-but
On the mechanism of reaction of tert-butoxyl radicals with dialkylphosphites
✍ G. Brunton; K. U. Ingold 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB

## Abstract It has been shown by ESR spectroscopy that the title reaction involves abstraction of hydrogen from the phosphite, since at −10°C the reaction has a kinetic deuterium isotope effect, k~H~/k~D~, or ∼3. The rate constant for hydrogen abstraction is __c__. 2 × 10^4^ M^−1^ s^−1^. There is n