Effect of the solvent viscosity on the rate of phenoxyl radical recombination
β Scribed by A. I. Burshtein; I. V. Khudyakov; P. P. Levin
- Book ID
- 112449103
- Publisher
- Springer
- Year
- 1980
- Tongue
- English
- Weight
- 357 KB
- Volume
- 29
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
We have studied the solvent effect on the ESR hyperfine splitting constants of some neutral radicals.
Flash photolysis technique has been used to obtain the rate and thermodynamic parameters of the reversible dimerization reactions of a range of ten phenoxy radicals (I-X) in a toluene-dibutylphthalate mixture (0.6 CP < TJ < 18.4 cF): The main reason for the difference in the k l values are the diff
## Abstract The overall activity of animal fatty acid synthetase at the saturation level of substrate concentration decreased when the solvent viscosity, Ξ·, of the reaction mixture was increased with viscogens such as glycerol, sucrose, and polyethylene glycol. The activity of the enzyme changed ro