Solvent effect on the rate of the Mannich reaction of butyraldehyde with formaldehyde
β Scribed by G. A. Marshalok; N. M. Karpyak; R. G. Makitra; I. P. Polyuzhin
- Book ID
- 111464087
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2006
- Tongue
- English
- Weight
- 149 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1070-4280
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π SIMILAR VOLUMES
The effect of the polarity of seven solvents (c = 2-60) on the rate of ozone reactions with stilbene and ally1 chloride has been studied. The data show that the rate of the reaction is insensitive to the medium polarity. The results of earlier publications are revised and are shown to be in agreemen
## Abstract The photooxidations of __n__βbutyraldehyde initiated by Cl atom were carried out at room temperature (298 Β± 2K) and 1 atm pressure. The rate coefficient for the reactions of Cl atom with __n__βbutyraldehyde was determined as __k__ = (2.04 Β± 0.36) Γ 10^β10^ cm^3^ molecule^β1^ s^β1^ by us