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Solvent Effect on the Rate of Dimerization of Cyclopentadiene

✍ Scribed by N. M. Karpyak; R. G. Makitra; G. A. Marshalok; O. Ya. Pal'chikova; I. I. Yatchishin

Publisher
Springer
Year
2005
Tongue
English
Weight
48 KB
Volume
75
Category
Article
ISSN
1070-3632

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Effect of solvent viscosity on the kinet
Effect of solvent viscosity on the kinetics of reversible dimerization of phenoxy radicals
✍ P. P. Levin; I. V. Khudyakov; V. A. Kuzmin πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 577 KB

Flash photolysis technique has been used to obtain the rate and thermodynamic parameters of the reversible dimerization reactions of a range of ten phenoxy radicals (I-X) in a toluene-dibutylphthalate mixture (0.6 CP < TJ < 18.4 cF): The main reason for the difference in the k l values are the diff