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Solvent effect in the addition of thetert-butyl radical to acrylonitrile

✍ Scribed by A. Salikhov; H. Fischer

Book ID
113000914
Publisher
Springer Vienna
Year
1993
Tongue
English
Weight
518 KB
Volume
5
Category
Article
ISSN
0937-9347

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Rates of addition of tert-butyl and piva
Rates of addition of tert-butyl and pivaloyl radicals to acrylonitrile measured by modulated ESR and ΞΌSR spectroscopy
✍ F. Jent; H. Paul; E. Roduner; M. Heming; H. Fischer πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 439 KB

For the rate constant of addition of tert-butyl radicals to acrylonitrile at T = 300 K in solution modulated ESR spectroscopy and muon spin rotation yield lo6 M-' s-' and 2.4 x lo6 M-' s-'. The addition of pivaloyl radical to acrylonitrile proceeds with Arrhenius parameters log AIM-' s-' = 7.7 and E