Solvent complexes of jet-cooled β-phenylethylamine
✍ Scribed by Jeffrey Sipior; Chin Khuan Teh; Mark Sulkes
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 435 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1053-0509
No coin nor oath required. For personal study only.
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Rotational spectra of the molecular ions HOCO ÷ and HOCS ÷, and the ion complexes, D~--Ar and sym-D2H÷-Ar were observed in a supersonic-jet expansion by using a Fabry-Perot type Fourier-transform microwave spectrometer cooperated with a pulsed discharge nozzle. Ion-formation efficiency for HOCS ÷ re
Laser-induced fluorescence excitation spectroscopy in a supersonic expansion is used to evidence intermolecular chiral discrimination at the microscopic level. Measurements have been performed in (R)-(+)-and (S)-(-)-et-methyl-2-naphthalenemethanol (a naphthalene compound made chiral by the asymmetri