Solvent- and Catalyst-Free Direct Aldol Reactions
✍ Scribed by Zongling Wang; Chengpan Zhang; Chuntao Zhang; Yan-Song Zheng; Jichang Xiao
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 73 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0256-7660
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📜 SIMILAR VOLUMES
## Abstract A solvent‐free asymmetric and direct __anti__‐aldol reaction of aliphatic ketones with aromatic aldehydes catalyzed by recyclable L‐prolineamides and L‐prolinethioamides **3** is studied. The L‐prolinethioamide **3d** (5 mol%), derived from L‐Pro and (__R__)‐1‐aminoindane, is the most e
## Abstract Polystyrene‐supported binam‐prolinamide (PSBP) is used as catalyst in the aldol reaction between several ketones and aldehydes under solvent‐free or aqueous conditions affording the corresponding aldol product in high regio‐, diastereo, and enantioselectivities.
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