ChemInform Abstract: Solvent-Free Asymmetric Direct Aldol Reactions Organocatalyzed by Recoverable (Sa)-Binam-L-prolinamide.
✍ Scribed by Gabriela Guillena; Maria del Carmen Hita; Carmen Najera; Santiago F. Viozquez
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 41 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Polystyrene‐supported binam‐prolinamide (PSBP) is used as catalyst in the aldol reaction between several ketones and aldehydes under solvent‐free or aqueous conditions affording the corresponding aldol product in high regio‐, diastereo, and enantioselectivities.
## Abstract Similar reactions in solution proceed with lower diastereo‐ and enantioselectivity.
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