Dimethylgold(III) complexes with the anions of glycine, alnnine, valine, cysteine, histidine and imidazole, benzimidazole and I ,2,4-triazole, respectively, have been prepared. The structures of the complexes are discussed on the basis of their infrared spectra.
Solvation of metal(III) complexes of maltol and related ligands
β Scribed by Emma Beatty; John Burgess; Marttand Patel
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 66 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0162-0134
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
but an unusually large second solvation shell such as Au(I). Investigations of metal ions coordinated to ammonia ligands have shown that coordination to hetero-atoms can accelerate the ligand exchange reaction rates by several orders of magnitude, e.g. for Cu(II) and Ni(II). Simulations of ions in a
Complexes of the type [(M(CO),),L/ (M = C'r or W, L = RS(CH&SR, R = Me and n = 6, R = Et andn=2or4;M=W,R=Meort-Buandn=2), fM(CO)5LJ (M = CF or W, L = MeSCH,Ph; M = Cr, L = EtS(CH&SEt) and [M(CO)4L] (M = Cr, MO or W, L = EtS(CH&SEt) have been isolated and characterised by i r., u.v.-visible and 'H n.