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Solvation of ions—enthalpies, entropies and free energies of transfer

✍ Scribed by A.J. Parker

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
880 KB
Volume
21
Category
Article
ISSN
0013-4686

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Solvation of ions—XX. The ferrocene—ferr
Solvation of ions—XX. The ferrocene—ferricinium couple and its role in the estimation of free energies of transfer of single ions
✍ John W. Diggle; A.J. Parker 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 520 KB

The ferrocene-ferricinium electrode (Pt/Foc. Fit') was investigated in water, acetonitrile, ethanol. DMSO and DMF using single scan cyclic voltammetry and phase sensitive ac polarography. The oxidation-reduction is pseudo-reversible in all five solvents with an electrochemical rate constant of appro