Solvation of halide ions with CH3OH in the gas phase
โ Scribed by Kenzo Hiraoka; Shinishi Yamabe
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 888 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0168-1176
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๐ SIMILAR VOLUMES
Gas-phase complexes of halide anions with a variety of crown ethers and acyclic analogs are formed by ion-molecule reactions in the chemical ionization source of a triple-quadrupole mass spectrometer. The ether complexes of iodide, bromide, and chloride dissociate on collisional activation by cleava
The reaction rates of SO3 with CH,OH in He were measured at total pressures of 0.7-1.6 torr in flow tubes. The concentration of SO3 was monitored by the SOz\* fluorescence from excitation of SO3 at 147 nm. The reaction rate constant of SO3 + CH30H in the gas phase is determined to be (1.17 ? 0.16) x
Molecular dynamics simulations have been performed on the collision between a cesium ion and a cluster of twenty methanol molecules. This process, generating a solvated ion, was studied over a range (I to 25 eV> of eight collision energies. Preliminary analysis of this gas phase solvation has includ