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Solvation in high-temperature aqueous electrolyte solutions

โœ Scribed by A.A. Chialvo; P.T. Cummings; J.M. Simonson; R.E. Mesme

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
565 KB
Volume
87
Category
Article
ISSN
0167-7322

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โœฆ Synopsis

We review the recently proposed molecular-based formalism for infinitely dilute nightemperature electrolyte solutions which establishes connections between the microscopic solvent environment around individual ionic species and their macroscopic solvation behavior. Then, we illustrate this formalism by interpreting some recent experimental results for infinitely dilute NaCl aqueous solutions. Finally, we discuss some theoretical implications, guided by the formalism, concerning the modeling of high-temperature aqueous-electrolyte solutions.

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