Solvation in aqueous N,N-dimethylformamide
β Scribed by J. Bougard; R. Jadot
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 211 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0021-9614
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π SIMILAR VOLUMES
Molecular dynamics simulations with new reliable quantum-chemically derived potential have been performed for Na + , K + , Cl -and Br -ions in liquid N,N-dimethylformamide (DMFA) at 233, 298, and 318 K. Structural properties of ion solvation shells were investigated through the radial distribution f
The thermal decomposition rate constant of AIBN ( k d ) in N,N-dimethylformamide (DMF)/ acrylonitrile (AN) mixtures of various compositions at 60Β°C is studied. The k d value is (6.45 +. 0.3) X min-' for pure acrylonitrile. The k d values of DMF/AN mixtures were found to be dependent on the mixture
Surhce-enkmced Rrtman spectra are reported from pyridme in ~,~-d~e~~lfor~~mide at a silver electrode. Potentialand time-dependent resnfts are presented and discussed in terms of the electrode surface morphology.