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Ion association and solvation of perchlorate salts in N,N-dimethylformamide and N,N-dimethylacetamide: A dielectric relaxation study

✍ Scribed by Bernhard Wurm; Michael Münsterer; Johannes Richardi; Richard Buchner; Josef Barthel


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
416 KB
Volume
119
Category
Article
ISSN
0167-7322

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## Abstract The solvation structure of magnesium, zinc(II), and alkaline earth metal ions in __N__,__N__‐dimethylformamide (DMF) and __N__,__N__‐dimethylacetamide (DMA), and their mixtures has been studied by means of Raman spectroscopy and DFT calculations. The solvation number is revealed to be 6