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Solvation Dynamics of Dipolar Probes in Dipolar Room Temperature Ionic Liquids: Separation of Ion−Dipole and Dipole−Dipole Interaction Contributions

✍ Scribed by Kashyap, Hemant K.; Biswas, Ranjit


Book ID
127329421
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
631 KB
Volume
114
Category
Article
ISSN
0022-3654

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Solvation of an ion and of a dipole in a
✍ Biman Bagchi; Amalendu Chandra 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 501 KB

Theoretical expressions for the time-dependent salvation energy of an ion and of a dipole in a dense dipolar liquid are derived from microscopic considerations. We show that in contradiction to the prediction of the continuum models, the dynamics of these two species are significantly different from