Solvation Dynamics in Room Temperature Ionic Liquids: Dynamics Stokes Shift Studies of Fluorescence of Dipolar Molecules
β Scribed by Prasun K. Mandal; Satyen Saha; Rana Karmakar; Anunay Samanta
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract We report a molecular dynamics study of the solvation of UO~2~^2+^, Eu^3+^ and Eu^2+^ ions in two βbasicβ (Lewis acidity) roomβtemperature ionic liquids (IL) composed of the 1βethylβ3βmethylimidazolium cation (EMI^+^) and a mixture of AlCl~4~^β^ and Cl^β^ anions, in which the Cl^β^/AlCl
The term 'ionic liquid' has come to indicate a class of molten organic salts that are liquid at room temperature and may contain bulky aromatic moieties such as imidazolium or heterocyclic pyridinium as cation and an inorganic anion such as PF 6 Γ , BF 4 Γ , [(CF 3 SO 2 ) 2 N] Γ , NO 3 Γ , etc. The