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Solution Equilibria. A Unified Mathematical Treatment of Potentiometric and Polarographic Data in a Metal–Ligand Equilibrium Study at a Fixed Ligand to Metal Ratio and Various pH Values

✍ Scribed by Ignacy Cukrowski; Geoffrey Ngigi

Book ID: 101380965
Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 192 KB
Volume: 13
Category: Article
ISSN: 1040-0397
DOI: 10.1002/1521-4109(200110)13:15<1242::aid-elan1242>3.0.co;2-j

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A new method of speciation by differential pulse polarography (DPP) is described. It is focused on non-labile complexes on the DPP time scale. By solving mass-balance equations -which are written for the labile part of a metal-ligand system -free metal, free ligand and non-labile complex concentrati

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ΔEp vs. pH Plot as a Source of Informati

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Evaluation of a Peak Potential of an Uncomplexed Metal Ion in Speciation Study of Labile Metal–Ligand Systems by Polarography. Stability Constant Determination of CdII and PbII with Picolinic Acid at a Fixed LT:MT Ratio and Varied pH

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The ligand picolinic acid was studied with Cd II and Pb II by differential pulse polarography (DPP) at fixed total ligand (L T ) to total metal (M T ) concentration ratios, varied pH at 25 ЊC and an ionic strength of m ¼ 0.1 and 0.5 mol dm ¹3 . The corrected peak potential of an uncomplexed metal io