ΔEp vs. pH Plot as a Source of Information in Polarographic Studies of Kinetically Labile Metal Complexes at a Constant Ligand to Metal Ratio

Formation constant calculation for non-l

Formation constant calculation for non-labile complexes based on a labile part of the metal-ligand system. A differential pulse polarographic study at fixed ligand to metal ratio and varied pH: application to polarographically inactive complexes

✍ Ignacy Cukrowski; Robert D. Hancock; Robert C. Luckay 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 947 KB

A new method of speciation by differential pulse polarography (DPP) is described. It is focused on non-labile complexes on the DPP time scale. By solving mass-balance equations -which are written for the labile part of a metal-ligand system -free metal, free ligand and non-labile complex concentrati