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Solution calorimetric, equilibrium, and synthetic studies of oxidative addition/reductive elimination of cyclopentadiene derivatives, C5R5H (R = H, Me, indenyl), to/from the metal complexes M(CO)3(RCN)3/(*5-C5R5)M(CO)3H (M = chromium, molybdenum, tungsten)

✍ Scribed by Kubas, Gregory J.; Kiss, Gabor.; Hoff, Carl D.


Book ID
126481693
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
955 KB
Volume
10
Category
Article
ISSN
0276-7333

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✍ Lothar Weber; Gabriel Noveski; Ulrich Lassahn; Hans-Georg Stammler; Beate Neuman 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 1 views

## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C