Solute-solvent interactions. I. Evaluations of relative activities of reference cations in acetonitrile and water
β Scribed by Coetzee, Johannes F.; Campion, James J.
- Book ID
- 126088426
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 635 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Absorption spectra of the superoxide ion have been studied in dimethylformamide (DMF) and acetonitrile (AN). It was found that the superoxide ion existed in equilibrium with an ion pair in AN (__K__~eq~ = 20__M__^β1^, Bu~4~N^+^ is the cation) and as βfreeβ (solvated) ion in DMF. The add
Ah&met-The equilibrium between I and the product restthing from the addition of ethanol to one of its C-N double bonds: 3-ethoxy-3,4-diphenyl-lJ,Qhiadisxohne 1,ldioxide (II), is studied by electrochemical methods in ethanol (EtOH)-acetonitrile (ACN) solvent mixtures. The equilibrium constant is meas