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The interaction of water-soluble cationic porphyrin meso-tetrakis@-N-methylpyridinyl)porphyrin (TMPyP) manganese derivatives with DNA was demonstrated by their catalytic activity on the luminol-H,O, chemiluminescence (CL) system. The catalytic activity of Mn-TMPyP on the CL reaction was markedly enh
The interaction of granaticin with two different yeast ribonucleic acids, dialyzed transfer RNA and calf thymus DNA was studied. Contrary to previous reports, no binding of granaticin to DNA or RNA was observed. The visible spectrum of granaticin on direct mixing or equilibrium dialysis of granatici
A study of the monomeric chromophore of the oligopeptides netropsin (1), distamycin III (2), and distamycin V (3) by polarization spectroscopy techniques and molecular orbital calculations is reported. Linear dichroism spectra of the monomeric model compounds 1-methyl-2(ethylcarbamoyl)-4-acetamido-p
Republic of Germany ## Synopsis The affinity of amino acid residues to nucleic acids is probed by measurements of melting temperatures t , for the helix-coil transition a t various concentrations of amino acid amides. The increase oft, on addition of ligand is described by the equation t , = t k