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Solubility parameters in polyoxetanes: Poly(oxetane), poly(3,3-dimethyl oxetane), and poly(3,3-diethyloxetane)

✍ Scribed by E. Perez; M. A. Gomez; A. Bello; J. G. Fatou


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
415 KB
Volume
27
Category
Article
ISSN
0021-8995

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The quasi-living cationic copolymerization of 3,3-bis(chloromethyl)oxetane (BCMO) and -caprolactone (-CL), using boron trifluoride etherate as catalyst and 1,4-butanediol as coinitiator, was investigated in methylene chloride at 0Β°C. The resulting hydroxyl-ended copolymers exhibit a narrow molecular