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Characterization of poly(3,3-bisethoxymethyl oxetane) and poly(3,3-bisazidomethyl oxetane) and their block copolymers

✍ Scribed by E. A. Murphy; T. Ntozakhe; C. J. Murphy; J. J. Fay; L. H. Sperling; G. E. Manser


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
929 KB
Volume
37
Category
Article
ISSN
0021-8995

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✍ Jean-Jacques Jutier; AnΓ©mone De Gunzbourg; Robert E. Prud'homme πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 217 KB

The quasi-living cationic copolymerization of 3,3-bis(chloromethyl)oxetane (BCMO) and -caprolactone (-CL), using boron trifluoride etherate as catalyst and 1,4-butanediol as coinitiator, was investigated in methylene chloride at 0Β°C. The resulting hydroxyl-ended copolymers exhibit a narrow molecular