The rate constants for the replacement of water from the inner-coordination shell of C O ( N H ~) ~O H ~~+ , I, by dimethyl sulfoxide (DMSO) as DMSO gradually replaced water in the solvation shell of I were found to approach, and finally equal, the water-exchange rate constant of I in aqueous media
β¦ LIBER β¦
Solubilities and solvation of aluminum (III), iron (III), and indium (III) 8-hydroxyquinolinates in methanol/water mixtures
β Scribed by J. Burgess; D. N. Drasdo; M. S. Patel
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 394 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0022-3549
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Epoxidation of Olefins by a Water-Soluble Iron(III) Porphyrin Complex and Hydroperoxides in Aqueous Solution. -Based on the results of the title reaction of (I) with different olefins (II)-(IV) and comparison with other oxidants the possible mechanism is discussed. Preliminary studies concerning ste