✍ Scribed by Felix Sirovski; Christian Reichardt; Marina Gorokhova; Sergei Ruban; Elena Stoikova
No coin nor oath required. For personal study only.
The applicability of the models developed earlier for the topochemical reactions in the solid/liquid phase-transfer catalysis is discussed. Depending on the solvent and the catalyst the reaction may be inhibited by the crust of the solid inorganic product. Solvents like MeCN and THF, and catalysts such as polyethylene glycols loosen this crust, thus preventing the inhibition. The solvent influence using the Er(30) parameter in different reactions in the solid/liquid system is investigated.
📜 SIMILAR VOLUMES
We present an analysis of mass transfer in solid-liquid phase-transfer catalysis (SLPTC), obtaining analytical solutions for the stagnant-film model and numerical solutions to the complete transport equations for the von K&-m&n rotating-disk flow. The latter is viewed as a prime candidate for experi
## Abstract Optimum conditions for the solid–liquid phase alkylation of methylenebis(diphenylphosphine oxide) (MBDPPO) and ethyl cyanomethylphosphonate (ECMP) were explored studying the role of phase transfer catalysis and microwave (MW) irradiation, as well as the effect of the cation of the alkal