✦ LIBER ✦

(Solid+liquid) phase equlibria and solid-compound formation in (trichloromethane+N,N-dimethylformamide, or pyridine, orN,N-dimethylaniline)

✍ Scribed by Guan-quan Che; Wen-lie Peng; Biao Che

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 158 KB
Volume: 29
Category: Article
ISSN: 0021-9614
DOI: 10.1006/jcht.1996.0172

No coin nor oath required. For personal study only.

✦ Synopsis

Solid + liquid) phase diagrams have been constructed for (trichloromethane + N,N-dimethylformamide, or pyridine, or N,N-dimethylaniline). Congruently melting solid addition compounds form with the empirical formulae: HCON(CH3)2•CHCl3 and C5H5N•CHCl3. The HCON(CH3)2•CHCl3 is interesting in that a metastable form can be made to crystallize from solution. No solid addition compound forms in 4(1 -x)CHCl3 + xC6H5N(CH3)25.

📜 SIMILAR VOLUMES

(Solid + liquid) phase equilibria and so

(Solid + liquid) phase equilibria and solid-compound formation in tetrachloromethane + furan, + pyridine, and + N-methylpyrrole

✍ Che Guanquan; J.Bevan Ott; J.Rex Goates 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 320 KB

(Solid + liquid) phase equilibria and so

(Solid + liquid) phase equilibria and solid-compound formation in (trichloromethane + cyclohexanone, or butanone, or 1-methyl-2-pyrrolidinone)

✍ Guan-quan Che; Zhong-qi Huang; Dan Li; Xi-lan Gu; San-lai Luo 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 306 KB

## 510275, P.R.C. (Solid+liquid) phase diagrams have been constructed for (trichloromethane+cyclohexanone, or butanone, or 1-methyl-2-pyrrolidinone). Solid addition compounds form with the empirical formulae: CHCl3•C6H10O, CHCl3•C5H9NO, (CHCl3)2•C4H8O, (CHCl3)2•C6H10O, and (CHCl3)2•C5H9NO. Compoun

(Solid + liquid) phase equilibria for (N

(Solid + liquid) phase equilibria for (N,N-dimethylacetamide + tetrachloromethane): enthalpies of melting of pure components and enthalpies for formation of molecular addition compounds from phase equilibria

✍ J.R Goates; J Boerio-Goates; S.R Goates; J.B Ott 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 326 KB

(Solid  +  liquid) equilibria

(Solid  +  liquid) equilibria and solid compound formation in (N-methyl-2-pyrrolidinone  +  benzene, or toluene, or 1,3,5-trimethylbenzene, or ethylbenzene, or chlorobenzene, or 1,2-dichlorobenzene, or 1,2,4-trichlorobenzene, or 1,1,1-trichloroethane, or dichloromethane)

✍ Urszula Domanska; Trevor M. Letcher 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 160 KB

All are congruently melting compounds. Compound formation is attributed to a charge-transfer interaction with the benzene, or chlorobenzene, or 1,2-dichlorobenzene, or 1,2,4-trichlorobenzene acting as electron acceptors and the nitrogen, or oxygen in N -methyl-2-pyrrolidinone acting as electron dono