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(Solid + liquid) phase equilibria and solid-compound formation in (trichloromethane + cyclohexanone, or butanone, or 1-methyl-2-pyrrolidinone)

✍ Scribed by Guan-quan Che; Zhong-qi Huang; Dan Li; Xi-lan Gu; San-lai Luo

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
306 KB
Volume
28
Category
Article
ISSN
0021-9614

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✦ Synopsis

510275, P.R.C.

(Solid+liquid) phase diagrams have been constructed for (trichloromethane+cyclohexanone, or butanone, or 1-methyl-2-pyrrolidinone). Solid addition compounds form with the empirical formulae: CHCl3β€’C6H10O, CHCl3β€’C5H9NO, (CHCl3)2β€’C4H8O, (CHCl3)2β€’C6H10O, and (CHCl3)2β€’C5H9NO. Compound formation is attributed to charge-transfer interaction for the first two compounds, and to hydrogen bonding for the last three.

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