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Solid-state transitions in crystalline tetracene

✍ Scribed by R. Jankowiak; J. Kalinowski; M. Konys; J. Buchert


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
469 KB
Volume
65
Category
Article
ISSN
0009-2614

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✦ Synopsis


Solid-state tmnsitions in crystalline tetmcene h%e been investigated b\ Raman spectroscopy and b> anisotropy of the effect of ZI magetic field on its prompt fluorescence. Discontinuous changes in the temperature dependence of Ramrtn lattice modes nnd new phonon lines occur nezu 182 zmd 144 K, signifying the occurrence OF two phase tnmsitions. The m&gnetic nnisotropy effect shows .I gmduai change with tempenture. suggesting the transition at 182 K is preceded by ZI continuous rotation of the intermoleculnr pIme_ * This uork hlls been p.utly supported by the Polish Aczxdem) of Sciences_


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