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Solid-state studies of α- and β-[Mo2Cl4(dppe)2]—kinetics of the α → β isomerization reaction and solid-state 31P and 13C NMR spectra

✍ Scribed by Andrew McVitie; Robert D. Peacock


Book ID
108428613
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
731 KB
Volume
11
Category
Article
ISSN
0277-5387

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✍ M. V. Galakhov; V. I. Bakhmutov; I. V. Barinov 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB

## Abstract Internal rotation about the C‐2–C‐3 bond was observed in the ^13^C CP‐MAS NMR spectra of the solid complexes [M~2~(ηHC^1^C^2^C^3^Me~2~)(CO)~4~(ηC~5~H~5~)~2~]^+^ [BF~4~]^−^ where M = Mo or W.