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Solid State NMR of Polymers

✍ Scribed by Cecil Dybowski (auth.), Lon J. Mathias (eds.)


Publisher
Springer US
Year
1991
Tongue
English
Leaves
406
Edition
1
Category
Library

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✦ Synopsis


The chapters in this collection are from papers which were presented at a symposium on solid-state NMR of polymers. A two-part program on available NMR techniques applicable to solid polymer analysis was presented at the 3rd Chemical Congress of North American held in Toronto, Ontario, June 5-10,1988. The program was sponsored by the Division of Polymer Chemistry with support provided by the Division, its Industrial Sponsors, and the Donors of the Petroleum Research Fund administered by the American Chemical Society. Co-organizers included Professor Colin Fyfe of the University of British Columbia (Vancouver, Canada), Professor Hans Spiess of the Max Planck Institut fur Polymerforschung (Mainz, West Germany), and myself. The full-day tutorial, which was free to registered attendees, covered the range of topics. The purpose of the tutorial was to provide a basic introduction to the field so that newcomers to its present and future applications could develop sufficient understanding to learn effectively from the subsequent symposium. The first talk attempted to give listeners a feel for the way a novice spectroscopist can learn to use the various NMR techniques to explore his own areas of interest. Simple experiments can provide unique information about solid polymers that can be useful in interpreting synthetic results and in relating solid-state conformation, morphology and molecular motion to physical properties.

✦ Table of Contents


Front Matter....Pages i-ix
Multiple-Pulse 1 H and 19 F NMR Techniques....Pages 1-21
Solid-State 2 H NMR: Overview with Specific Examples....Pages 23-60
Application of NMR Imaging to Polymers: A Tutorial....Pages 61-79
Solid State 13 C NMR Studies of the Structures, Conformations, and Dynamics of Semi-Crystalline Polymers....Pages 81-105
CP/MAS 13 C NMR Analysis of Poly(Arylene Methylene)s....Pages 107-116
Radiation Induced Morphological Changes in a Semi-Crystalline Polymer: A 13 C NMR Study....Pages 117-130
13 C NMR Studies of Poly(Vinylidene Fluoride) Blends....Pages 131-144
Solid State NMR Detection of Molecular-Level Mixing Phenomena in Strongly Interacting Polymer Blends and Phase-Separated Copolymers....Pages 145-165
CP-MAS NMR Spectra of Poly(N-Vinylcarbazole) and of its Charge Transfer Complexes: Preliminary Investigation....Pages 167-177
13 C NMR of Crosslinked Poly(Methacrylic Anhydride)....Pages 179-200
Application of Solid State 13 C NMR Spectroscopy to Sulfur Vulcanized Natural Rubber....Pages 201-213
A Solid-State 13 C NMR Study of Polysiloxane Side-Chain Liquid Crystalline Polymers Containing 2-[4-(2S)-Methyl-Butoxy)-Phenyl]-5-(Ο‰-Alkyl)-1,3,2-Dioxaborinane with Alkyl Being Undecanyl and Octyl....Pages 215-232
VT-MAS NMR as a Probe of Molecular Mobility and Local Composition: Solidified Acrylic Dispersions....Pages 233-244
Molecular Motion in Crystalline and Mesomorphous Phases of Large Size Cycloalkanes as a Model for Polyethylene....Pages 245-259
Solid State NMR Relaxation Study of Liquid Crystal Polymers Employing a Two-Dimensional Technique....Pages 261-270
Dynamics of Surface Bound Polymers and Coupling Agents....Pages 271-281
Solid-State 2 H and 13 C NMR Study of the Structure of Polyanilines....Pages 283-294
The Solid State 29 Si and 13 C NMR of Poly(Di- n -Alkylsilylenes)....Pages 295-304
29 Si and 13 C Magic Angle Sample Spinning Nuclear Magnetic Resonance Spectroscopy of Ceramic Fibers Prepared by Pyrolysis of Organosilicon Polymers....Pages 305-320
Variable-Temperature Solid-State NMR of Polyphosphazenes....Pages 321-330
Hydrogen Cyanide Polymers: Solid State NMR ( 15 N, 13 C) Investigations....Pages 331-342
1 H NMR Imaging of Solids with Magic Angle Spinning....Pages 343-361
NMR Imaging: Application to Elastomeric Materials....Pages 363-375
NMR Imaging Investigations of Case II Diffusion in Polymers....Pages 377-386
Application of One-Dimensional NMR Imaging to Solvent Diffusion Measurements in Polymeric Samples....Pages 387-397
Back Matter....Pages 399-408

✦ Subjects


Inorganic Chemistry; Organic Chemistry; Polymer Sciences; Characterization and Evaluation of Materials


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